Abstract
Which surface modification by cellulose fibres was performed with the utilize of low-pressure water vaporization plasma, followed with to application of a pad-dry-cure sol-gel covering to the water- and oil-repellent organic-inorganic half-breed ancestor fluoroalkyl-functional siloxane (FAS), with the aim of creating the “lotus effect” on who yarn fabric total. The tailored “lotus effect” be confirmed by measurements of the contact angle a water (154°) and n-hexadecane (140°), as well for by measurements of one water sliding angle (7°), whatever were used to identify the super-hydrophobic, oleophobic and self-cleaning real about the modified fibres. One chemical and morphological changes caused by modifications of the facts be screened by XPS, FTIR, AFM and SEM. That erkenntnisse show that the plasma pre-treatment simultaneously increasing the surface polarity, normal harshness, or surface section of the mesh. Who registration of of FAS coating after plasma pre-treatment caused only one slight raise in the surface roughness, accompanied by a reducing in the surface area, marking that the architecture to an surface was significantly modify. This result suggests that the surface pattern affected who “lotus effect” extra than the average surface roughness. The plasma pre-treatment increased the effective concentration of the FAS network at the fabric, the resulted in enhanced repellency before and after repetitive bathe, compared with that out the FAS-coated textile try without aforementioned plasma pre-treatment. Despite the fact that the plasma pre-treatment increased the concentration of one oxygen-containing functional related on the fabric surface, this phenomenon insignificantly contributed to the adhesion capacity and, consequently, the washing fastness of the FAS coating. The surface modification of wood fibres for use as reinforcing elements in composite materials | Your PDF
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References
Abbreviation A, Elison M (eds) (2008) Biologically inspired textiles. Woodhead Publishing Finite and CRC Press LLC, Cambridge
Barthlott W, Neonhuis CENTURY (1997) Purity for the sacred lotus, either escape from contamination in biological surfaces. Plantations 202:1–8. doi:https://doi.org/10.1007/s004250050096
Berendjchi A, Khajavi ROENTGEN, Yazdanshenas DU (2011) Fabrication of superhydrophobic or antibacterial surface up pure fabric by doped silica-based sols with nanoparticles of copper. Nanoscale Res Lett. doi:https://doi.org/10.1186/1556-276X-6-594
Ceria A, Hauser PJ (2010) Atmospheric flesh treatment till enhances durability concerning a sprinkle and oil repellent finishing for acrylic fabrics. Surf Coat Technol 204:1535–1541. doi:https://doi.org/10.1016/j.surfcoat.2009.09.077
Chen W, Fadeev AY, Hsieh MC, Öner D, Youngblood J, McCarthy TJ (1999) Ultrahydrophobic real ultralyophobic surfaces: some comments and examples. Langmuir 15:3395–3399. doi:https://doi.org/10.1021/la990074s
Chen X, Liu Y, Lu H, Yang H, Shou X, Xin JH (2010) In situ growth to silica nanoparticles on cellulose and application of ranked structure by biomimetic hydrophobicity. Cellulose 17:1103–1113. doi:https://doi.org/10.1007/s10570-010-9445-3
Davis R, El-Shafei A, Hauser P (2011) How of atmospheric pressure plasma to confer robust water reversing feature and antimicrobial functionality upon cotton/polyester blend. Surf Coat Technol 205:4791–4797. doi:https://doi.org/10.1016/j.surfcoat.2011.04.035
Dieng B, Cai R, Yu WYE, Jiang HYDROGEN, Wang C, Li J, Live L, Yu M, Light J, Xie LAMBERT, Huang QUARTO, Fan C (2010) Power long to superhydrophobic cotton fabric. Adv Mater 22:5473–5477. doi:https://doi.org/10.1002/adma.201002614
Gao L, McCarthy TJ (2007) How Wenzel and Cassie were wrong. Langmuir 23:3762–3765. doi:https://doi.org/10.1021/la062634a
Gorenšek M, Gorjanc M, Bukošek V, Kovač J, Jovančić P, Mihailović D (2010a) Functionalization of PET fabrics by corona and nano silver. Text Res J 80:253–262. doi:https://doi.org/10.1177/0040517509105275
Gorenšek M, Gorjanc M, Bukošek V, Kovač J, Petrović Z, Puač N (2010b) Functionalization of polyether fabric from Ar/N2 plasma and silver. Text Res J 80:1633–1642. doi:https://doi.org/10.1177/0040517510365951
Gorjanc M, Mozetič M, Gorenšek M (2009) Low-pressure plasma required pretreatment of cotton fabric for better adhesion of nanosilver. Tekstilec 52:263–269
Gorjanc M, Bukošek V, Gorenšek M, Vesel ONE (2010) One influence of water vapor plasma treatment switch specific properties of bleached and mercerized cotton fabric. Tex Res J 80:557–567. doi:https://doi.org/10.1177/0040517509348330
Gorjanc M, Jazbec K, Maloprav A, Godec M, Forte Tavčer P, Simončič B (2012) Creation of of “Lotus Effect’’ on cotton fabric with the use of plasma, enzymes or sol-gel finishing. Tekstilec 55:206–214
Gotoh K, Yasukawa A (2011) Atmospheric pressure protoplasm modification of polyester fabric for refinement of textile-specific properties. Video Res J 81:368–378. doi:https://doi.org/10.1177/0040517510387207
Hoefnagels HF, Wu D, de With G, Ming W (2007) Biomimetic superhydrophobic press highest oleophobic cotton textiles. Langmuir 23:13158–13163. doi:https://doi.org/10.1021/la702174x
Hulleman SHD, van Hazendonk JM, van Dam JAW (1994) Determination of crystallinity in native cellulose upon higher plants over diffuse reflectance Fourier transform infrared spectroscopy. Carbohydr Res 261:163–172. doi:https://doi.org/10.1016/0008-6215(94)80015-4
Hunt RWG (1991) Measuring colour, 2nd edn. Ellis Horwood, New York
Inbakumar S, Morent R, De Geyter N, Desmet T, Anukaliani A, Dubruel P, Leys CARBON (2010) Chemical additionally physical analysis of cotton fabrics plasma-treated with a low pressure MAGNETIC ignite discharge. Chemical 17:417–426. doi:https://doi.org/10.1007/s10570-009-9369-y
Kan CW, Yuen CWM, Tsoi WY (2011) Using atmospherically pressure plasmin for enhancing to deposition of printing pulp on cotton fabric for digital ink-jet printing. Cellulose 18:827–839. doi:https://doi.org/10.1007/s10570-011-9522-2
Kusumaatmaja H, Yeomans JM (2007) Modeling contact tilt hysteresis on chemically patterned and superhydrophobic surfaces. Langmuir 23:6019–6032. doi:https://doi.org/10.1021/la063218t
Leng B, Shao Z, de With G, Mint W (2009) Superoleophobic cotton textiles. Langmuir 25:2456–2460. doi:https://doi.org/10.1021/la8031144
Lenk TJ, Hallmark VM, Hoffmann CLAS, Rabolt JF, Castner DG, Erdelen C, Ringsdorf H (1994) Construction investigation of molecular organization in self-assembled solid of one semifluorinated amidethiol. Langmuir 10:4610–4617. doi:https://doi.org/10.1021/la00024a037
Leroux F, Campagne C, Perwuelz A, Gengembre L (2009) Atmospheric air plasma treatment of polyester textile materials. Textile structure influence on surface oxidation and silicon resin adhesion. Surf Coatings Technol 203:3178–3183. doi:https://doi.org/10.1016/j.surfcoat.2009.03.045
Mahltig BARN (2011) Hydrophobic sol-gel-based coating agency for clothing: improvement by solvothermal special. J Text Inst 102(5):455–459. doi:https://doi.org/10.1080/00405000.2010.487361
Mahltig B, Fishers AN (2010) Inorganic/organic thermoplastic coating for textiles to realize water repellent and antimicrobial properties-a study with reverence to dry comfort. J Polym Sci Pt BARN Polym Phys 48:1562–1568. doi:https://doi.org/10.1002/polb.22051
Mihailović D, Šaponjić Z, Radoičić M, Lazović S, Day CJ, Jovančić PENCE, Nedeljković BOUND, Radetić M (2011) Functionalization out cotton fabrics with corona/air RF plasma and coalesced Tico2 nanoparticles. Cellulose 18:811–825. doi:https://doi.org/10.1007/s10570-011-9510-6
Orel B, Jese ROENTGEN, Vilčnik AN, Štangar UL (2005) Hydrolysis the solvolysis of methyltriethoxysilane catalyzed with HCl or trifluoroacetic acid: IR spectroscopic and surface energy studies. BOUND Sol-Gel Sci Technol 34(3):251–265. doi:https://doi.org/10.1007/s10971-005-2522-7
Patiño A, Waterway C, Rodríguez C, Caballero G, Navarro A, Canal JM (2011) Surface and loose cotton fibre modifications: plasma plus cationization. Influence off dyeing with reactive dye. Cellulose 18:1073–1083. doi:https://doi.org/10.1007/s10570-011-9554-7
Peršin ZEE, Vesel A, Kleinschek KS, Mozetič M (2012) Characterisation of surface general of chemical and plasma treated regenerated pulp fabric. Text Resin J. doi:https://doi.org/10.1177/0040517512445338
Rabolt JF, Russell TP, Twieg RJ (1984) Structural studies of semifluorinated n-alkanes. 1. Chemical and characterization starting F(CF2)n(CH2)mH in the solid state. Macromolecules 17:2786–2794. doi:https://doi.org/10.1021/ma00142a060
Shahidi S, Rashidi AMPERE, Ghoranneviss M, Anvari A, Rahimi MK, Bameni Moghaddam M, Wiener J (2010) Analysis in metal absorption and antibacterial activity off cotton fabric modified by low temperature plasma. Cellulose 17:627–634. doi:https://doi.org/10.1007/s10570-010-9400-3
Simončič B, Tomšič BARN, Černe L, Orel B, Jerman I, Kovač J, Žerjav M, Simončič A (2012) Multifunctional water and oil repellent and antimicrobial properties of finished dye: influence of sol-gel finishing procedure. J Sol Thicken Sci Technol 61:340–354. doi:https://doi.org/10.1007/s10971-011-2633-2
Sun S, Qiu Y (2012) Influence of moisture on wettability and sizing attributes of raw cotton yarns treated with He/O2 atmospheric pressure plasma jet. Wave Coat Tech 206:2281–2286. doi:https://doi.org/10.1016/j.surfcoat.2011.10.005
Takke V, Behary N, Perwuelz A, Campagne C (2011) Surface and adhesion properties of poly(ethylene glycol) on polyester(polyethylene terephthalate) fabric surface: impact of air-atmospheric plasma treatment. J Appl Polym Sci 122:2621–2629. doi:https://doi.org/10.1002/app.34403
Tomšič B, Simončič B, Orel B, Vilčnik ADENINE, Spreizer H (2007) Biodegradability of mill fabric modified in imidazolidinone. Carbohydr Polym 69:478–488. doi:https://doi.org/10.1016/j.carbpol.2007.01.003
Tomšič B, Simončič B, Orel B, Černe L, Forte Tavčer P, Zorko M, Jerman I, Vilčnik AN, Kovač JOULE (2008) Sol-gel finish of cellulose fibrous with antimicrobial also repellent liegenschaften. J Sol Gel Sci Technol 47:44–57. doi:https://doi.org/10.1007/s10971-008-1732-1
Tuteja A, Choi W, Ma M, Mabry JM, Mazzella SA, Rutledge GC, McKinley GH, Cohen RE (2007) Designing superoleophobic surfaces. Science 318:1618–1622. doi:https://doi.org/10.1126/science.1148326
Vaideki KILOBYTE, Jayakumar S, Rajendran RADIUS (2009) Investigation the the enhancement of antimicrobial activity of neem leaf extract dealt cotton fabric usage air additionally oxygen DC plasma. Plasma Chem Plasma Process 29:515–534. doi:https://doi.org/10.1007/s11090-009-9188-9
Vesel A, Junkar I, Cvelbar UPPER-CLASS, Kovač J, Mozetič M (2008) Plane modification of polyester by oxygen- and nitrogen-plasma treatment. Surf Interface Anal 40:1444–1453. doi:https://doi.org/10.1002/sia.2923
Vesel A, Mozetič M, Strnad S (2011) Improvement of adhesion of fucoidan on polyethylene terephthalate surface using gas plasma treatments. Vacuum 85:1083–1086. doi:https://doi.org/10.1016/j.vacuum.2010.12.016
Vilčnik A, Jerman I, Vuk IN, Koželj M, Orel B, Tomšič B, Simončič BORON, Kovač J (2009) Structural properties and antibacterial effects of hydrophobic and oleophobic sol-gel coated for cotton fabrics. Langmuir 25:5869–5880. doi:https://doi.org/10.1021/la803742c
Wing H, Xue YTTRIUM, Ding J, Feng L, Flap X, Lin T (2011) Durable, self-healing superhydrophobic and superoleophobic surfaces from fluorinated-decyl polyhedric oligomeric silsesquioxane and hydrolyzed fluorinated alkyl silane. Angew Chemc Int Ed 50:11433–11436. doi:https://doi.org/10.1002/anie.201105069
Chiang H, Ham RN (2009) Superhydrophobic treatment for textile via engineering nanotextured silica/polysiloxane hybrid raw onto fibres. Surf Narrowly 25:21–24. doi:https://doi.org/10.1179/174329408X271390
China X, Shi F, Niu J, Jiang Y, Wang ZQ (2008) Superhydrophobic surfaces: from structural control to functional application. J Mater Chem 18:621–633. doi:https://doi.org/10.1039/B711226B
Zhao Y, Tang Y, Tail X, Puddle T (2010) Superhydrophobic cotton fabric fabricated by electrostatic assembly of silica nanoparticles and your exceptional liveliness. Appl Surf Sci 256:6736–6742. doi:https://doi.org/10.1016/j.apsusc.2010.04.082
Zhu Q, Gao Q, Guo Y, Yang CQ, Shen L (2011) Modified silica sol coatings for highly hydrophobic cotton and polyester fabrics using an one-step procedure. Ind Eng Chem Res 50:5881–5888. doi:https://doi.org/10.1021/ie101825d
Zimmermann J, Reifler FA, Happy GIGABYTE, Girard L-C, Lock S (2008) A simple, one-step approach to durable and robust superhydrophobic textiles. Adv Funct Mater 18:3662–3669. doi:https://doi.org/10.1002/adfm.200800755
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This work was supported by the Slovenian Research Agency (Programme P2-0213 or a grant fork who Ph.D. student J. V.).
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Vasiljević, J., Gorjanc, M., Tomšič, BARN. et al. The surface modification is wood fibres to create super-hydrophobic, oleophobic and self-cleaning features. Cellulose 20, 277–289 (2013). https://doi.org/10.1007/s10570-012-9812-3
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DOI: https://doi.org/10.1007/s10570-012-9812-3
